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APET电(Dian)催(Cui)化(Hua)氧(Yang)化(Hua)设(She)备(Bei)
APET电(Dian)催(Cui)化(Hua)氧(Yang)化(Hua)设(She)备(Bei)
电(Dian)催(Cui)化(Hua)氧(Yang)化(Hua)原(Yuan)理(Li):(?)
电(Dian)催(Cui)化(Hua)氧(Yang)化(Hua)以(Yi)电(Dian)场(Chang)存(Cun)在(Zai)为(Wei)基(Ji)础(Chu)条(Tiao)件(Jian),(?)水(Shui)环(Huan)境(Jing)中(Zhong)的(De)有(You)机(Ji)污(Wu)染(Ran)物(Wu)在(Zai)具(Ju)有(You)催(Cui)化(Hua)活(Huo)性(Xing) 的(De)电(Dian)极(Ji)材(Cai)料(Liao)上(Shang)进(Jin)行(Xing)直(Zhi)接(Jie)阳(Yang)极(Ji)氧(Yang)化(Hua)或(Huo)以(Yi)电(Dian)极(Ji)表(Biao)面(Mian)产(Chan)生(Sheng)的(De)强(Qiang)氧(Yang)化(Hua)性(Xing)活(Huo)性(Xing)物(Wu)质(Zhi)为(Wei)媒(Mei)介(Jie)进(Jin)行(Xing)电(Dian)化(Hua)学(Xue)矿(Kuang)化(Hua)。(?)同(Tong)时(Shi),(?)电(Dian)催(Cui)化(Hua)氧(Yang)化(Hua)技(Ji)术(Shu)以(Yi)电(Dian)子(Zi)为(Wei)反(Fan)应(Ying)中(Zhong)介(Jie),(?)勿(Wu)需(Xu)添(Tian)加(Jia)额(E)外(Wai)氧(Yang)化(Hua)剂(Ji),(?)最(Zui)终(Zhong)将(Jiang)有(You)机(Ji)污(Wu)染(Ran)物(Wu)转(Zhuan)化(Hua)为(Wei)其(Qi)他(Ta)物(Wu)质(Zhi)或(Huo)矿(Kuang)化(Hua)为(Wei)羧(Suo)酸(Suan)分(Fen)子(Zi)、(?)CO2和(He)水(Shui),(?)电(Dian)催(Cui)化(Hua)氧(Yang)化(Hua)技(Ji)术(Shu)已(Yi)被(Bei)作(Zuo)为(Wei)当(Dang)前(Qian)时(Shi)代(Dai)最(Zui)具(Ju)实(Shi)际(Ji)应(Ying)用(Yong)前(Qian)景(Jing)的(De)高(Gao)级(Ji)氧(Yang)化(Hua)技(Ji)术(Shu)之(Zhi)一(Yi),(?)其(Qi)在(Zai)水(Shui)环(Huan)境(Jing)中(Zhong)有(You)机(Ji)物(Wu)的(De)处(Chu)理(Li)上(Shang)的(De)潜(Qian)在(Zai)的(De)应(Ying)用(Yong)前(Qian)景(Jing)也(Ye)被(Bei)越(Yue)来(Lai)越(Yue)多(Duo)的(De)后(Hou)继(Ji)者(Zhe)进(Jin)一(Yi)步(Bu)研(Yan)究(Jiu)和(He)验(Yan)证(Zheng)。(?)
((?)1)(?)直(Zhi)接(Jie)氧(Yang)化(Hua) 直(Zhi)接(Jie)氧(Yang)化(Hua)通(Tong)常(Chang)为(Wei)体(Ti)系(Xi)中(Zhong)的(De)有(You)机(Ji)污(Wu)染(Ran)物(Wu)直(Zhi)接(Jie)与(Yu)阳(Yang)极(Ji)活(Huo)性(Xing)物(Wu)质(Zhi)进(Jin)行(Xing)电(Dian)子(Zi)转(Zhuan)移(Yi)反(Fan) 应(Ying),(?)达(Da)到(Dao)转(Zhuan)化(Hua)或(Huo)消(Xiao)除(Chu)污(Wu)染(Ran)物(Wu)的(De)目(Mu)的(De)。(?)具(Ju)体(Ti)步(Bu)骤(Zhou)如(Ru)下(Xia),(?)首(Shou)先(Xian),(?)水(Shui)在(Zai)阳(Yang)极(Ji) M 表(Biao)面(Mian)放(Fang)电(Dian)形(Xing)成(Cheng)的(De)强(Qiang)氧(Yang)化(Hua)性(Xing)OH以(Yi)吸(Xi)附(Fu)的(De)形(Xing)式(Shi)存(Cun)在(Zai)阳(Yang)极(Ji)材(Cai)料(Liao) M 上(Shang),(?)即(Ji) M(OH),(?)在(Zai)此(Ci)过(Guo)程(Cheng)中(Zhong)OH 主(Zhu)要(Yao)以(Yi)化(Hua)学(Xue)吸(Xi)附(Fu)形(Xing)式(Shi)存(Cun)在(Zai)于(Yu)电(Dian)极(Ji)表(Biao)面(Mian);(?)接(Jie)着(Zhuo),(?)经(Jing)过(Guo)上(Shang)一(Yi)步(Bu)反(Fan)应(Ying)吸(Xi)附(Fu)的(De)OH发(Fa)生(Sheng)电(Dian)子(Zi)转(Zhuan)移(Yi)反(Fan)应(Ying)将(Jiang)氧(Yang)原(Yuan)子(Zi)传(Chuan)输(Shu)给(Gei)阳(Yang)极(Ji)材(Cai)料(Liao) M,(?)形(Xing)成(Cheng)更(Geng)高(Gao)价(Jia)态(Tai)的(De)氧(Yang)化(Hua)物(Wu) MO;(?)最(Zui)后(Hou),(?)具(Ju)有(You)强(Qiang)氧(Yang)化(Hua)活(Huo)性(Xing)的(De) MO 与(Yu)体(Ti)系(Xi)中(Zhong)的(De)有(You)机(Ji)污(Wu)染(Ran)物(Wu) R 进(Jin)行(Xing)反(Fan)应(Ying)发(Fa)生(Sheng)电(Dian)化(Hua)学(Xue)转(Zhuan)化(Hua)将(Jiang)有(You)机(Ji)污(Wu)染(Ran)物(Wu)质(Zhi) R 转(Zhuan)化(Hua)为(Wei) RO,(?)同(Tong)时(Shi) MO 被(Bei)还(Huan)原(Yuan)至(Zhi)最(Zui)初(Chu)的(De)阳(Yang)极(Ji)材(Cai)料(Liao)状(Zhuang)态(Tai) M,(?)继(Ji)续(Xu)进(Jin)行(Xing)循(Xun)环(Huan)以(Yi)上(Shang)过(Guo)程(Cheng)。(?)
((?)2)(?)间(Jian)接(Jie)氧(Yang)化(Hua) 间(Jian)接(Jie)氧(Yang)化(Hua)是(Shi)以(Yi)电(Dian)极(Ji)表(Biao)面(Mian)生(Sheng)成(Cheng)的(De)具(Ju)有(You)强(Qiang)氧(Yang)化(Hua)活(Huo)性(Xing)物(Wu)质(Zhi)为(Wei)媒(Mei)介(Jie)氧(Yang)化(Hua)体(Ti)系(Xi)中(Zhong)的(De)有(You) 机(Ji)污(Wu)染(Ran)物(Wu) R,(?)最(Zui)终(Zhong)达(Da)到(Dao)矿(Kuang)化(Hua)水(Shui)体(Ti)系(Xi)中(Zhong)有(You)机(Ji)物(Wu)的(De)功(Gong)效(Xiao),(?)根(Gen)据(Ju)具(Ju)体(Ti)的(De)电(Dian)解(Jie)质(Zhi),(?)阳(Yang)极(Ji)表(Biao)面(Mian)产(Chan)生(Sheng)的(De)强(Qiang)氧(Yang)化(Hua)活(Huo)性(Xing)物(Wu)质(Zhi)一(Yi)般(Ban)包(Bao)含(Han)OH、(?)Cl O-、(?)O3等(Deng),(?)但(Dan)在(Zai)水(Shui)溶(Rong)液(Ye)体(Ti)系(Xi)一(Yi)般(Ban)表(Biao)现(Xian)为(Wei)OH,(?)同(Tong)时(Shi)阴(Yin)阳(Yang)两(Liang)极(Ji)还(Huan)可(Ke)协(Xie)同(Tong)增(Zeng)加(Jia)有(You)机(Ji)物(Wu)的(De)电(Dian)催(Cui)化(Hua)氧(Yang)化(Hua)效(Xiao)率(Lu)。(?)
电(Dian)催(Cui)化(Hua)氧(Yang)化(Hua)技(Ji)术(Shu)特(Te)点(Dian):(?)
去(Qu)除(Chu)率(Lu)高(Gao),(?)最(Zui)高(Gao)达(Da)到(Dao)接(Jie)近(Jin)100%;(?)
工(Gong)艺(Yi)设(She)备(Bei)相(Xiang)对(Dui)简(Jian)单(Dan),(?)操(Cao)作(Zuo)方(Fang)便(Bian):(?)基(Ji)本(Ben)构(Gou)成(Cheng)只(Zhi)有(You)电(Dian)极(Ji),(?)电(Dian)源(Yuan)和(He)容(Rong)器(Qi)((?)反(Fan)应(Ying)器(Qi))(?);(?)
工(Gong)艺(Yi)参(Can)数(Shu)控(Kong)制(Zhi)自(Zi)动(Dong)化(Hua)程(Cheng)度(Du)高(Gao),(?)调(Diao)节(Jie)精(Jing)准(Zhun)快(Kuai)捷(Jie):(?)只(Zhi)要(Yao)获(Huo)取(Qu)进(Jin)出(Chu)水(Shui)的(De)相(Xiang)关(Guan)数(Shu)据(Ju),(?)通(Tong)过(Guo)控(Kong)制(Zhi)电(Dian)流(Liu)大(Da)小(Xiao)就(Jiu)能(Neng)调(Diao)整(Zheng)处(Chu)理(Li)效(Xiao)果(Guo);(?)
对(Dui)水(Shui)质(Zhi)的(De)适(Shi)应(Ying)性(Xing)强(Qiang):(?)电(Dian)化(Hua)学(Xue)反(Fan)应(Ying)对(Dui)有(You)机(Ji)污(Wu)染(Ran)物(Wu)的(De)作(Zuo)用(Yong)没(Mei)有(You)选(Xuan)择(Ze)性(Xing),(?)一(Yi)般(Ban)不(Bu)添(Tian)加(Jia)化(Hua)学(Xue)药(Yao)剂(Ji),(?)适(Shi)用(Yong)于(Yu)各(Ge)种(Zhong)有(You)机(Ji)污(Wu)染(Ran)废(Fei)水(Shui)的(De)处(Chu)理(Li);(?)
降(Jiang)解(Jie)彻(Che)底(Di),(?)绿(Lu)色(Se)环(Huan)保(Bao):(?)不(Bu)是(Shi)污(Wu)染(Ran)物(Wu)的(De)转(Zhuan)移(Yi)而(?)是(Shi)降(Jiang)解(Jie);(?)不(Bu)产(Chan)生(Sheng)污(Wu)泥(Ni),(?)没(Mei)有(You)浓(Nong)缩(Suo)液(Ye)、(?)基(Ji)本(Ben)上(Shang)没(Mei)有(You)二(?)次(Ci)污(Wu)染(Ran);(?)
功(Gong)能(Neng)多(Duo)样(Yang):(?)兼(Jian)有(You)消(Xiao)毒(Du)杀(Sha)菌(Jun),(?)气(Qi)浮(Fu)、(?)絮(Xu)凝(Ning)等(Deng)多(Duo)种(Zhong)功(Gong)能(Neng);(?)
适(Shi)用(Yong)领(Ling)域(Yu):(?)
炼(Lian)焦(Jiao),(?)煤(Mei)化(Hua)工(Gong)废(Fei)水(Shui);(?)纺(Fang)织(Zhi)印(Yin)染(Ran)行(Xing)业(Ye)废(Fei)水(Shui);(?)生(Sheng)化(Hua)尾(Wei)水(Shui) ;(?)制(Zhi)革(Ge)皮(Pi)毛(Mao)加(Jia)工(Gong)行(Xing)业(Ye)废(Fei)水(Shui);(?)石(Shi)油(You)化(Hua)工(Gong)废(Fei)水(Shui);(?)钢(Gang)铁(Tie)工(Gong)业(Ye)废(Fei)水(Shui);(?)农(Nong)药(Yao)工(Gong)业(Ye)废(Fei)水(Shui)等(Deng)。(?)